原子转移自由基聚合(英語:Atom-transfer radical-polymerization,簡稱ATRP)是一种新的活性聚合反应。与原子转移自由基加成反应一样,在原子转移自由基聚合中,二种不同的催化方法可形成碳-碳、碳-硫、碳-氮等键。一是自由基催化,另一是金属催化。基于历史缘由,人们现在所说的原子转移自由基聚合就是金属催化的原子转移自由基聚合。正如其名称所指示,在原子转移自 … WebApr 11, 2012 · Current status and future perspectives in atom transfer radical polymerization (ATRP) are presented. Special emphasis is placed on mechanistic understanding of ATRP, recent synthetic and process development, and new controlled polymer architectures enabled by ATRP.
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2.11: Living Radical Polymerization- ATRP - Chemistry LibreTexts
WebOct 18, 2024 · Reversible addition–fragmentation chain-transfer (RAFT) polymerization and atom transfer radical polymerization (ATRP) are the two most common controlled radical polymerization methods. Both... WebSep 14, 2011 · Detailed mechanistic studies reveal that halogen exchange (HE) in ATRP can occur not only by a radical pathway (atom transfer) but also by an ionic pathway (SN2 reaction) because Cu(I)(L)X and Cu(II)(L)X2 complexes contain weakly associated halide anion that can participate in the SN2 reaction with alkyl halide (ATRP initiator). Both … WebOrganocatalyzed Atom Transfer Radical Polymerization. Organocatalyzed atom transfer radical polymerization (O-ATRP) is a controlled radical polymerization methodology mediated by an organic photoredox catalyst, enabling light to drive the synthesis of polymers with defined composition and architecture. Unique to other … free abortion clinics in pensacola